Electrical equipment should be nonsparking or explosion proof. Firefighting measures these containers hold gas under pressure, with no liquid phase. Disclaimer statement this information is furnished without warranty, expressed or implied, as to accuracy or completeness. Earthground and bond all lines and equipment associated with the hydrogen system. Liquefied natural gas, material safety data sheet, revision date, page 4 11. Shipment of compressed gas cylinders that have been filled without the owner. Information contained in this material safety data sheet msrds is believed to be reliable but no representation, guarantee or warranties of any kind are made as to accuracy, suitability for a particular application or results to be obtained from them. Download the safety nitnem path in pdf data sheets sds for boc products gases, to ensure you and your team are well informed.
Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and smoking should be prohibited in areas where this material is. Do not rely on sense of smell alone to determine if there is a gas leak or if gas is otherwise present. Workplace hazardous materials information system whmis as required by law, this pamphlet is provided to update your health and safety information about natural gas. Handle sealed gas cylinders in accordance with cga p1, safe handling of compressed gases in. Irrigate eyes for at least 15 minutes with copious quantities of water, keeping eyelids apart and away from.
The information is obtained from various sources including the. Dihydrogen, parahydrogen, refrigerant gas r702, water gas. Download the safety nitnem path in pdf data sheets sds for boc. Remove containers from area of fire if safe to do so. Our calibration gas sds information includes material identification, physicalchemical characteristics, fire and exposure hazardous data, reactivity hazardous data, precautions for safe handling and use, and control measures.
Other exposure guidelines vacated limits revoked by the court of appeals decision in aflcio v. Msa pn 10028062 calibration check gas, 40 ppm hydrogen sulfide in nitrogen msds. Stop flow of gas if safe to do so, while continuing cooling water spray. Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. This msds is also available electronically on our website. Inhalation inhaling the vapour may cause drowsiness and dizziness. Exposure controls personal protection engineering measures provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below. Relevant identified uses of the subs tance or mixture and uses advised against use of the substancemixture. Rescuers should be taken for medical attention if necessary. Structural firefighters protective clothing provides limited protection in fire. Dihydrogen, parahydrogen, refrigerant gas r702, water gas 1. Section 2 hazards identification ghs classification flammable gas, category 1 gas under pressure, compressed gas acute toxicity inhalation, category 4 95% unknown ghs label elements symbols signal word danger. Details of the supplier of the safety data sheet praxair, inc. If irritation of the skin develops after exposure to this gas mixture, immediately begin decontamination with.
Irrigate eyes for at least 15 minutes with copious quantities of water, keeping eyelids apart and away from eyeballs during irrigation. Refrigerated liquefied gas h281 simple asphyxiant hazards not otherwise classified health hazard frostbite label elements osha hcs 2012 danger hazard statements extremely flammable gas h220 contains refrigerated gas. Handling and storage advice on general occupational hygiene conditions for safe storage, including any incompatibilities eating, drinking and. The suitability of this product as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the physiological effects, methods employed. Humans breathing up to 8 ppm of hydrogen sulfide over a two month period experienced nausea, headache, shortness of breath, sleep disturbance, eye and throat irritation. Most important symptoms and effects, both acute and delayed eye contact direct contact with this liquefied gas may burn the eyes. Never recompress a gas or a gas mixture without first consulting the. Gas fires should not be extinguished unless flow of gas can be immediately stopped. If involved in a major fire, they should be sprayed with water to. Gas detection equipment should be used, particularly when working in confined areas. May cause skin, eye, and respiratory tract irritation asphyxiant at high concentrations may cause central nervous system depression contents under pressure keep at temperatures below 52c 125f material safety data sheet. P271 use only outdoors or in a wellventilated area. None of the trace impurities of this gas contribute significantly to the hazards associated with the product.
Hydrogen, compressed gas safety data sheet sds p4604. If you have questions or concerns about the whmis legislation, please contact your local ministry of labour office. For questions about the material safety data sheet for this or other halliburton products, contact chemical compliance at 15802514335. For additional recommendations consult compressed gas associations cga.
Includes tips on safe handling, and information useful to emergency response and other medical personnel. P210 wear cold insulating gloves, face shield andor eye protection. Do not extinguish, unless leak can be stopped safely. Material safety data sheets provide information about the composition, characteristics and potential hazards of gaseous hydrogen. When involved in a fire, this gas will ignite and produce toxic gases including carbon monoxide. Relevant identified uses of the substance or mixture and uses advised against 1. Nitrous oxide, compressed safety data sheet p4636 this sds conforms to u. Gas compressed gas contains gas under pressure may. Cgapg02 protect from sunlight when ambient temperature exceeds 52c 125f. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Store in cool, dry, wellventilated area of noncombustible. Chemical product and company identification product name.
Material safety data sheet imperial college london. Read and follow all safety data sheets sdss before use. All hazard information pertinent to this product has been provided in this material safety data sheet, per the requirements of the federal occupational safety and health administration standard 29 cfr 1910. Msds material safety data sheet for gaseous hydrogen h2 by universal industrial gases, inc.
Nitrogen, gas, material safety data sheet, revision date 31aug2010, page 3 8. Wear appropriate respirator when ventilation is inadequate. Material safety data sheet southern california gas company. The main health hazard associated with releases of this gas is asphyxiation, by displacement of. Gas cabinets, with appropriate exhaust treatment, are recommended, as is automatic monitoring of the secondary enclosures and work areas for release. Calibration gas sds calibration gas mixture sds supplier. Identification product identifier product name natural gas synonyms natural gas dry. Nitrous oxide, compressed safety data sheet sds p4636. Perpaerd may 205 1 material safety data sheet for natural gas hazardous ingredients. Safety data sheet ghs product identifier other means of identification product type section 1. Praxair material safety data sheet see section 15, under tsca, for important restrictions on product use. Compressed gas high concentrations may exclude oxygen and cause dizziness and suffocation. Details of the supplier of the safety data sheet emergency telephone number 2.
Compressed gas h280 classification according to whs regulation 1. Safety data sheet carbon monoxide air liquidegasekatalog. Precautionary statements prevention keep away from heat, sparks, open flames andor hot surfaces. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit. Other companies are charging thousands of dollars to set up accounts and give you access to. For additional recommendations consult compressed gas associations cga safety bulletin sb2, oxygendeficient atmospheres. Methane is inactive biologically and essentially nontoxic. P280 wear eye protection, face protection, protective gloves, protective clothing. Below is a list of our most common calibration gas mixtures sdss. Ne not established c ceiling limit see section 16 for definitions of terms used. Wear positive pressure selfcontained breathing apparatus scba. Relevant identified uses of the substance or mixture and uses advised against use of the substancemixture. Pipeline gas sds numbergrade ng 200801 relevant identified uses of the substance or mixture and uses advised against.
Under certain conditions, the distinctive odorant added to natural gas may be diminished or lost so that it cannot be smelled. Hydrogen is a colorless, odorless, flammable gas or a colorless, odorless, cryogenic liquid. Nitrogen is a colorless, odorless, nonflammable gas, or a colorless, odorless, cryogenic liquid. Move containers from fire area if you can do it without risk. Methane is not listed in the iarc, ntp or by osha as a carcinogen or potential carcinogen. A cylinder rupture hazard exists when this gas mixture, which is under pressure, is subject to heat or flames. Skin contact contact with the product may cause frostbite. Cylinders should be stored upright with valve protection cap in place and firmly secured to prevent falling. Never attempt to transfer gases from one cylindercontainer to another. Osha, cma, ansi and canadian whmis standards part i what is the material and what do i need to know in an emergency. Take a copy of the label and the msds to physician or other health professional with victims. Never recompress a gas or a gas mixture without first consulting the supplier. Conditions for safe storage, including any incompatibilities.
Safety data sheet natural gas southern california gas. Primarily methane gas with other fossil fuels such as ethane, propane, butane and pentane. Use water spray to cool surroundings and exposures. Material safety data sheet gasoline, all grades msds no. Shipment of compressed gas cylinders that have been filled without the owners consent is a violation of federal law 49 cfr 173. Identification product identifier product name natural gas synonyms natural gasdry. The main health hazard associated with releases of this gas is asphyxiation, by displacement of oxygen. Msa pn 10028062 calibration check gas, 40 ppm hydrogen. Nitrogen is not listed as a marine pollutant by dot. In case of frostbite, obtain immediate medical attention. Your new online msds binder is a place for you to store the. A hazard from reignition or explosion exists if the flame is extinguished without stopping flow of gas andor cooling surroundings and eliminating ignition source. Nitrous oxide, compressed weizmann institute of science. An overview of the chemical make up and identifies the many procedures and proper handling of natural gas.
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